ORGANOMETALLIC MOLYBDENUM(V) COMPLEXES WITH PRIMARY PHOSPHANE LIGANDSSYNTHESES, SPECTROSCOPIC PROPERTIES, AND CRYSTAL-STRUCTURES OF [CP'MOCL4(PH2R)] (R=2,4,6-(PR3C6H2)-C-I, CYCLOHEXYL, CP'=C5H4ME)

Authors
FELSBERG R BLAUROCK S JELONEK S GELBRICH T KIRMSE R VOIGT A HEYHAWKINS E
Citation
R. Felsberg et al., ORGANOMETALLIC MOLYBDENUM(V) COMPLEXES WITH PRIMARY PHOSPHANE LIGANDSSYNTHESES, SPECTROSCOPIC PROPERTIES, AND CRYSTAL-STRUCTURES OF [CP'MOCL4(PH2R)] (R=2,4,6-(PR3C6H2)-C-I, CYCLOHEXYL, CP'=C5H4ME), Chemische Berichte, 130(6), 1997, pp. 807-812
Citations number
47
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
130
Issue
6
Year of publication
1997
Pages
807 - 812
Database
ISI
SICI code
0009-2940(1997)130:6<807:OMCWPP>2.0.ZU;2-K
Abstract
[Cp'MoCl4(CH3CN)] (Cp' = C5H4Me) reacts with 2,4,6-triisopropylphenylp hosphane or cyclohexylphosphane to give the phosphane complexes [Cp'Mo Cl4(PH2R)] [R = 2,4,6-(Pr3C6H2)-C-i (1), Cy (2)]. 1 and 2 were charact erized spectroscopically (IR, MS) and by crystal structure determinati ons. EPR investigations in Liquid and frozen solution confirmed the pr esence of Mo(V) species and the data were used to analyze the spin-den sity distribution in the first coordination sphere.