Parallel solid-phase synthesis, screening, and encoding strategies for olefin-polymerization catalysts

Authors
Boussie, TR Murphy, V Hall, KA Coutard, C Dales, C Petro, M Carlson, E Turner, HW Powers, TS
Citation
Tr. Boussie et al., Parallel solid-phase synthesis, screening, and encoding strategies for olefin-polymerization catalysts, TETRAHEDRON, 55(39), 1999, pp. 11699-11710
Citations number
39
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
55
Issue
39
Year of publication
1999
Pages
11699 - 11710
Database
ISI
SICI code
0040-4020(19990924)55:39<11699:PSSSAE>2.0.ZU;2-U
Abstract
A solid-phase protocol has been developed that allows for the parallel synt hesis, screening, and chemical encoding of nickel (II) and palladium (II) o lefin-polymerization catalysts. These catalysts display activity profiles c omparable to the analogous homogeneous catalyst systems prepared by traditi onal methods. A chemical encoding strategy has also been developed which en ables the chemical history of pooled solid-phase catalysts to be evaluated. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.