Reactions of peroxynitrite with N,N-dimethyl-p-toluidine and 1,4-naphthoquinone. Evidence for heterolytic cleavage of a nitrogen-oxygen bond in peroxynitrous acid

Authors
Nonoyama, N Hisatome, K Shoda, C Suzuki, H
Citation
N. Nonoyama et al., Reactions of peroxynitrite with N,N-dimethyl-p-toluidine and 1,4-naphthoquinone. Evidence for heterolytic cleavage of a nitrogen-oxygen bond in peroxynitrous acid, TETRAHEDR L, 40(38), 1999, pp. 6939-6940
Citations number
4
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
38
Year of publication
1999
Pages
6939 - 6940
Database
ISI
SICI code
0040-4039(19990917)40:38<6939:ROPWNA>2.0.ZU;2-3
Abstract
Peroxynitrite (ONOO-) has been found to react with the title amine 1 and qu inone 5 to form N-nitrosoamine 2 and 2,3-epoxide 6, respectively, in accord with the in situ generation of the nitrosonium and hydroperoxide ions as t he respective reactive species. (C) 1999 Elsevier Science Ltd. All rights r eserved.