Low-temperature selective oxidation of hydrogen sulfide into elemental sulfur on a NiS2/SiC catalyst

Citation
N. Keller et al., Low-temperature selective oxidation of hydrogen sulfide into elemental sulfur on a NiS2/SiC catalyst, CATAL LETT, 61(3-4), 1999, pp. 151-155
Citations number
23
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
CATALYSIS LETTERS
ISSN journal
1011372X → ACNP
Volume
61
Issue
3-4
Year of publication
1999
Pages
151 - 155
Database
ISI
SICI code
1011-372X(1999)61:3-4<151:LSOOHS>2.0.ZU;2-6
Abstract
Nickel sulfide supported on SiC exhibits a very high activity and selectivi ty for the direct oxidation of H2S into elemental sulfur at low reaction te mperature (60 degrees C). The presence of water on the catalyst surface cou ld explain the absence of deactivation even at high sulfur loading of the s urface. The chemical inertness of the SiC support allowed any detrimental r eactions between the active phase and the support itself to be avoided.