(NBu4n+)(3)[Re6S8Cl6](3-center dot): synthesis and luminescence of the paramagnetic, open shell member of a hexanuclear chalcohalide cluster redox system

Authors
Guilbaud, C Deluzet, A Domercq, B Molinie, P Coulon, C Boubekeur, K Batail, P
Citation
C. Guilbaud et al., (NBu4n+)(3)[Re6S8Cl6](3-center dot): synthesis and luminescence of the paramagnetic, open shell member of a hexanuclear chalcohalide cluster redox system, CHEM COMMUN, (18), 1999, pp. 1867-1868
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
18
Year of publication
1999
Pages
1867 - 1868
Database
ISI
SICI code
1359-7345(19990921):18<1867:(DSALO>2.0.ZU;2-4
Abstract
The chemical and electrochemical synthesis, X-ray crystal structure, magnet ic characterization, absorption and luminescence spectra of (NBu4n)(3)[Re6S 8Cl6], the 23-electron cluster core member of the reversible redox couple [ Re6S8Cl6](4-)-[Re6S8Cl6](3-.) is reported.