Macropolyhedral boron-containing cluster chemistry. The [SB17H19](-) anion: a nido-ten-vertex: arachno-ten-vertex cluster architecture and the first single-sulfur macropolyhedral thiaborane
T. Jelinek et al., Macropolyhedral boron-containing cluster chemistry. The [SB17H19](-) anion: a nido-ten-vertex: arachno-ten-vertex cluster architecture and the first single-sulfur macropolyhedral thiaborane, CHEM COMMUN, (18), 1999, pp. 1905-1906
Reaction of syn-B18H22 with metabisulfite gives a good yield of the first s
ingle-sulfur macropolyhedral thiaborane, the [SB17H19](-) anion, which exhi
bits the unusual arachno-nido two-borons-in-common cluster fusion mode.