Kw. Wong et al., Negative electron affinity on polycrystalline diamond surface induced by lithium fluoride deposition, DIAM RELAT, 8(10), 1999, pp. 1885-1890
Lithium fluoride (LiF) was deposited on hydrogenated and oxygenated polycry
stalline diamond surfaces. Lowering of the work function induced by the dip
ole effect of LiF was clearly observed using UV photoemission spectroscopy
and Kelvin probe. The decrease of the work function was sufficiently large
so that negative electron affinity was induced. This shows that the LIF ove
rlayer on diamond acts as an effective dipole layer to lower the surface wo
rk function of the diamond film. (C) 1999 Elsevier Science S.A. All rights
reserved.