To verify if the quantitative composition of volatiles arising from lipoxyg
enase pathway was affected by the olive fruit stones, oils from whole olive
s and from the pulp-only tissues, respectively, were submitted to gas chrom
atographic determination of volatile compounds extracted by dynamic head-sp
ace. Results showed different quantitative compositions for the two oil kin
ds because of the greater accumulation of C-6 compounds from the lipoxygena
se pathway in oils obtained from de-stoned olives, which is related to seri
ous: cellular disruption observed in the crushed pulp tissues, C-5 compound
s were affected by the stone removal from fruits. Furthermore, the enzymati
c oxidation of linoleic acid was promoted in oils obtained after removing f
ruit stones because of the more:significant increase of the concentrations
of corresponding C-6 metabolites. (C) 1999 Elsevier Science Ltd. All rights
reserved.