We investigate the effects of structural asymmetry on the electronic and op
tical properties of indium gallium nitride (InGaN) quantum wells (QW's), Us
ing a pulsed current excitation technique, spectral blue shift as large as
80 meV is observed in a strained 3.0-nm In0.2Ga0.8N QW as the pulsed curren
t increases from 1 mA to 1A. Based on a self-consistent calculation, me are
able to quantify a gain competition process among the interactions of piez
oelectricity, many-body, charge screening, and band filling effects. Such i
nteractions are shown to provide a mechanism for shaping the QW confined po
tential such that superior carrier confinement and charge screening of-the
piezoelectric field can be obtained in the asymmetric InGaN QW. At high car
rier injection of N-inj > 2 x 10(19) cm(-3), a tenfold increase in the TE-p
olarized optical gain can be achieved by using the asymmetric GaN-InGaN-AlG
aN QW instead of the symmetric InGaN-AlGaN QW. Due to the diminishing of pi
ezoelectricity-induced quantum-confined Stark effect, the calculated optica
l gain spectra of the asymmetric InGaN QW exhibit a spectral blue shift wit
h respect to those of the symmetric InGaN QW.