Synthesis and characterization of hypervalent organosilicon compounds

Authors
Singh, MS Bhagwat, VW Raju, MD Tiwari, SK
Citation
Ms. Singh et al., Synthesis and characterization of hypervalent organosilicon compounds, I J CHEM A, 38(7), 1999, pp. 716-719
Citations number
31
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
38
Issue
7
Year of publication
1999
Pages
716 - 719
Database
ISI
SICI code
0376-4710(199907)38:7<716:SACOHO>2.0.ZU;2-N
Abstract
Tri-, di- and monoorganosilicon(IV) derivatives of benzilmonothiosemicarbaz one have been synthesized by the reactions of the corresponding tri-, di- a nd monoorganosilicon(IV) chlorides with the sodium salt of benzilmonothiose micarbazone in different molar ratios. These derivatives have been characte rised by elemental analyses, molecular weights, conductivity measurements a nd spectral (IR, H-1 and C-13 NMR) studies. The complexation occurs through sulphur and the nitrogen of the >C=N group.