We have developed a fit method that allows detailed analysis of complicated
ellipsometric spectra, such as those of thick (similar to 10 mu m) multila
yer structures found in modern integrated optics devices. Ellipsometry shou
ld be the natural choice for thorough nondestructive characterisation of th
ose heterostructures, but extraction of the required parameters is often im
practicable by common approaches. Our fit procedure is based in spline para
metrisations of the unknown optical functions and is applicable to material
s either with a smooth optical response or displaying sharp electronic tran
sitions in the analysed energy range. We have applied our method to charact
erise PECVD-grown non-stoichiometric silicon oxides (SiOx) and thick wavegu
ide structures based on these materials.