J. Santiso et al., Structured YBa2Cu3O7-delta thin films grown on aligned calcium stabilized zirconia-calcium zirconate lamellar eutectic substrates, J PHYS IV, 9(P8), 1999, pp. 307-311
In this paper we present a new approach to obtain structured biepitaxial fi
lms by using eutectic substrates. In particular we have deposited YBa2Cu3O7
-delta (YBCO) thin films grown by Metal-Organic Chemical Vapor Deposition (
MOCVD) on eutectic Ca-stabilized Zirconia - CaZrO3, (CSZ-CZO) substrates st
ructured in the form of parallel lamellae. The films reproduce the pattern
of the substrate rind show ordered arrays of alternating c-axis and (103)-o
riented YBCO strips. Crystallographic characterisation reveals that YBCO fi
lms grow epitaxially on both eutectic phases. The structured films were ana
lysed by EPMA, and micro-Raman. The films show anisotropic transport proper
ties in both normal (resistivity anisotropy rho(T)/rho(L) (300K) approximat
e to 1.9) and superconducting states (critical current anisotropy at 77K J(
c)(L)/J(c)(T) approximate to 13) when measured along (L) or transverse (T)
to the substrate lamellae. Transport along transverse direction showed a co
nsiderably higher sensitivity to applied magnetic field than measurements i
n the longitudinal direction. This was attributed to the weak-link behaviou
r of the artificially-induced grain boundaries between strips.