A totally new technique of surface modification-thermal surface-alloying tr
eatment for pure copper-was developed. A 0.2-1.8 mm copper alloy layer, whi
ch has a hardness 4 to 5 times higher than the pure copper substrate, was f
ormed after the treatment. The significance of this technique is that the s
urface of pure copper can be efficiently hardened without significant reduc
tion of the overall thermal and electrical conductivity. Variations of comp
osition and microstructure in the alloy layer were studied after pure coppe
r was surface ahoy treated with aluminum.