Isothermal sections in the Cr-Ga-N system in the 650-1000 degrees C temperature range

Citation
L. Farber et Mw. Barsoum, Isothermal sections in the Cr-Ga-N system in the 650-1000 degrees C temperature range, J MATER RES, 14(6), 1999, pp. 2560-2566
Citations number
21
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF MATERIALS RESEARCH
ISSN journal
08842914 → ACNP
Volume
14
Issue
6
Year of publication
1999
Pages
2560 - 2566
Database
ISI
SICI code
0884-2914(199906)14:6<2560:ISITCS>2.0.ZU;2-C
Abstract
Isothermal sections at 670, 740, and 800 degrees C in the Cr-Ga-N ternary s ystem were investigated. Details of the Cr-Ga and Cr-N binary phase diagram s were confirmed, and the equilibrium diagrams were constructed. At all tem peratures, Cr3GaN was in equilibrium with all the condensed phases, except GaN. In the 670-800 degrees C temperature range, Cr2GaN appears to be kinet ically stable in contact with GaN. This led to the construction of behavior diagrams that are valid only as long as GaN is present in the initial mixt ure. Above similar to 910 degrees C, Cr2GaN decomposes to form Cr3GaN, CrN, and Ga(1). At 1000 degrees C, Cr3GaN is in equilibrium with all the conden sed phases, and CrN is in equilibrium with Ga.