High-temperature powder x-ray diffraction of yttria to melting point

Powder x-ray diffraction data of yttria (Y2O3) were obtained from room temp erature to melting point with the thin wire resistance heating technique. A solid-state phase transition was observed at 2512 +/- 25 K and melting of the high-temperature phase at 2705 +/- 25 K. Thermal expansion data for alp ha-Y2O3 (C-type) are given for the range 298-2540 K. The unit cell paramete r increases nonlinearly, especially just before the solid-state transition. The x-ray diffraction spectrum of the high-temperature phase is consistent with the fluorite-type structure (space group Fm3) with a refined unit cel l parameter a = 5.3903(6) Angstrom at 2530 K. The sample recrystallized rap idly above 2540 K, and above 2730 K, all the diffraction lines and spots di sappeared from the x-ray diffraction spectrum that suggests complete meltin g.