The photo-stimulated diffusion of Ag in a-germanium sulfide is studied to o
btain low relief resist masks for the purposes of diffractive optics. The t
hickness of the photodoped layer is found to be proportional to the illumin
ation energy. An average chemical composition of the photodoping product, r
eproducible and constant in all photodoped areas is observed. This indicate
s the occurrence of a stoichiometric reaction as well as a step-like mechan
ism for the diffusion of Ag into the chalcogenide.