Hydrogen and fluorine adsorption on the h-BN (001) plane

The adsorption of H or F species on B vs N atoms on the h-BN (001) surface has been investigated theoretically within the DFT method, using a cluster approach. Only the boron atoms were subjected to a local transformation fro m hexagonal to cubic phase. It occurred either upon the adsorption of F spe cies or the adsorption of H species. For the latter situation, a neighborin g surface B atom was substituted by a C atom and, hence, the number of elec trons in the system was increased. The nitrogen atoms did not undergo, with one exception, any phase transformation. The adsorption of H species resul ted in a local transformation from sp(2) to sp(3) hybridization with a here by connected negative adsorption energy (-55 kJ/mol). This adsorption proce ss is therefore highly unlikely to occur in a CVD synthesis.