The influence of a magnetic field in 3-color S-step photoionization of Gd a
toms was investigated theoretically and experimentally for various combinat
ions of laser polarizations. The photoionization process was analyzed by so
lving the density matrix equations in which the influences of a magnetic fi
eld and the polarizations of the lasers were taken into account. It was fou
nd that the ionization dynamics of complex Gd atoms was sensitive to the re
lative polarizations of the lasers and that applying a magnetic field to Gd
atoms further increases the ionization efficiency for the schemes for dedu
cing angular momentum values. The strength of the magnetic field, as well a
s the relative polarizations of the lasers, could be optimized for better i
onization efficiency when linearly polarized lasers were used.