Safe operating region of chemical reactors in which exothermic and endothermic reactions proceed simultaneously - Tracking function approach

Citation
Sr. Lee et al., Safe operating region of chemical reactors in which exothermic and endothermic reactions proceed simultaneously - Tracking function approach, KAG KOG RON, 25(5), 1999, pp. 747-751
Citations number
5
Categorie Soggetti
Chemical Engineering
Journal title
KAGAKU KOGAKU RONBUNSHU
ISSN journal
0386216X → ACNP
Volume
25
Issue
5
Year of publication
1999
Pages
747 - 751
Database
ISI
SICI code
0386-216X(199909)25:5<747:SOROCR>2.0.ZU;2-S
Abstract
A safe operating region in which the state of a complete mixing type reacto r moves spontaneously towards a stable steady state without manipulative ac tion is determined by the tracking function analysis. The tracking function, which is a linear combination of temperature and con centration of reactant, is displayed with a straight line on the phase plan e and the line moves with time in the direction predicted by the derivative of the tracking function with respect to time. If straight line segments w hich correspond to tracking functions are assemble to form a closed polygon around a stable steady state on the phase plane and each segment moves tow ards the steady state as time passes, then the polygon manifests a boundary of safe operating region. Safe operating regions of the reactor in which dehydration and decompositio n of methanol proceed simultaneously are shown with a tetragon and a heptag on around the stable steady states.