Spatially resolved NMR in polymer science

Citation
B. Blumich et al., Spatially resolved NMR in polymer science, MACRO SYMP, 141, 1999, pp. 83-93
Citations number
28
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR SYMPOSIA
ISSN journal
10221360 → ACNP
Volume
141
Year of publication
1999
Pages
83 - 93
Database
ISI
SICI code
1022-1360(199906)141:<83:SRNIPS>2.0.ZU;2-I
Abstract
Selected applications of spatially resolved NMR are presented, which demons trate the use of the method for investigating applied topics relevant to po lymer and materials science. Examples are given for imaging of rigid, soft, and fluid matter. They include characterization and interpretation of elec trical aging in poly(ethylene), cross-link density at the interface of covu lcanized elastomer sheets, and cross-filtration in hollow-fiber filler modu les. A novel NMR dectector, the NMR-MOUSE, has been developed for process a nd quality control by relaxation measurements. Its use for non-destructive determination of the glass-transition temperature by room temperature measu rements on elastomer samples is demonstrated.