High resolution X-ray diffraction and X-ray topography study of GaN thin fi
lms, grown on sapphire (11.0) substrate by reduced pressure metalorganic va
por phase epitaxy (MOVPE) under various conditions, were performed. The str
ained lattice parameters, stress, misorientation and dislocation density of
GaN films were estimated. The experimental stress compares well with the t
heoretical stress obtained from the difference in the thermal expansion coe
fficient between the film and substrate. The dislocation density was found
to be highest in the thinner GaN film. It was also higher in the film witho
ut any buffer layer. For the same carrier concentration, the mobility of on
e of the film was lower than the other which could be due to the presence o
f higher dislocation density. Slip lines associated with dislocations, stac
king faults, cellular structure of dislocations and double positioning boun
daries were found in the X-ray topography from the GaN films. (C) 1999 Else
vier Science S.A. All rights reserved.