Yh. Gao et al., A HIGH-RESOLUTION ELECTRON-MICROSCOPY STUDY OF BLUE-LIGHT-EMITTING BETA-SIC NANOPARTICLES IN C-IMPLANTED SILICON(), Journal of materials research, 12(6), 1997, pp. 1640-1645
A high-resolution electron microscopy study of beta-SiC nanoparticles
formed by C+-implantation of single crystal silicon with subsequent an
nealing has been carried out. The as-implanted sample had a trilayered
structure, in which the surface layer, A, and the bottom layer, C, we
re crystalline but damaged, and the middle layer, B, was amorphous. Af
ter annealing this structure, beta-SiC particles were formed throughou
t the trilayered structure but with different forms: a few epitaxial b
eta-SiC nanoparticles in layers A and C, and more random nanoparticles
in layer B. The beta-SiC nanoparticles, in the size range 2-8 nm, sho
uld be responsible for the blue-emitting effect of the silicon-based p
orous beta-SiC.