Spectral and luminescent properties of mixed ligand cyclometalated complexes of Pd(II)

Authors
Puzyk, MV Antonov, NV Ivanov, YA Balashev, KP
Citation
Mv. Puzyk et al., Spectral and luminescent properties of mixed ligand cyclometalated complexes of Pd(II), OPT SPECTRO, 87(2), 1999, pp. 277-279
Citations number
14
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
OPTICS AND SPECTROSCOPY
ISSN journal
0030400X → ACNP
Volume
87
Issue
2
Year of publication
1999
Pages
277 - 279
Database
ISI
SICI code
0030-400X(199908)87:2<277:SALPOM>2.0.ZU;2-T
Abstract
On the basis of the analysis of absorption and luminescence spectra and the luminescence kinetics, the orbital nature and the main photophysical param eters of cyclometalated palladium complexes [Pd((CN)-N-boolean AND)L] in so lutions are studied. The orbital nature and the properties of lower excited electronic states of the complexes that are responsible for luminescence a re shown to be dependent on the nature of a cyclometalating ligand and a me tal.