Direct observation of reversible C(sp(3))-H bond activation. Characterization of the structures of both Ir complexes before and after C-H bond activation by using a flexible P-N heterochelate hybrid ligand

Authors
Kataoka, Y Imanishi, M Yamagata, T Tani, K
Citation
Y. Kataoka et al., Direct observation of reversible C(sp(3))-H bond activation. Characterization of the structures of both Ir complexes before and after C-H bond activation by using a flexible P-N heterochelate hybrid ligand, ORGANOMETAL, 18(18), 1999, pp. 3563-3565
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
18
Year of publication
1999
Pages
3563 - 3565
Database
ISI
SICI code
0276-7333(19990830)18:18<3563:DOORCB>2.0.ZU;2-6
Abstract
Direct observation of reversible C-H bond activation of a C(sp(3))-H bond i s shown for the Ir(I) complex 2a, which has a coordinatively flexible heter ochelate hybrid PNn=1 ligand (la). Full characterization data for the Ir(I) and Ir(III) complexes, including their X-ray structures and estimation of the thermodynamic and kinetic parameters for the C-H bond activation, are p rovided.