Angular correlation of positron annihilation radiation (ACPAR) along differ
ent crystallographic directions in GaP1-xNx is calculated. It is observed t
hat the electron-positron momentum density increases rapidly with increasin
g nitrogen content. The computational technique used here is based on the i
ndependent-particle model (IPM) coupled with the use of the electron pseudo
-wave function and the virtual crystal approximation (VCA) which incorporat
es compositional disorder as an effective potential. The variation of the p
ositron lifetime in these alloys is also presented.