Proton NMR spectroscopy investigation of the (C4H9NH3)(2)SnCl6 and (C12H25NH3)(2)SnCl6 hexachlorostannates

Authors
Elleuch, H Kamoun, M Daoud, A Reau, JM Senegas, J
Citation
H. Elleuch et al., Proton NMR spectroscopy investigation of the (C4H9NH3)(2)SnCl6 and (C12H25NH3)(2)SnCl6 hexachlorostannates, PHYS ST S-B, 214(1), 1999, pp. 141-151
Citations number
24
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
PHYSICA STATUS SOLIDI B-BASIC RESEARCH
ISSN journal
03701972 → ACNP
Volume
214
Issue
1
Year of publication
1999
Pages
141 - 151
Database
ISI
SICI code
0370-1972(199907)214:1<141:PNSIOT>2.0.ZU;2-6
Abstract
The structural transitions in (C4H9NH3)(2)SnCl6 and (C4H9NH3)(2)SnCl6 have been studied by proton NMR spectroscopy. The temperature dependences of the proton magnetic resonance absorption spectra have been determined and also those of the second moment (M-2). For the former compound, the phase trans ition was found to be connected with the motions of SnCl62- octahedra disto rtion. NH3 group reorientation and diffusion of chain defects dominate the nuclear resonance relaxation results in the latter compound.