Phase equilibria of a lattice model of associating binary mixtures

Citation
Jmr. Enrique et al., Phase equilibria of a lattice model of associating binary mixtures, PCCP PHYS C, 1(18), 1999, pp. 4271-4275
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PCCP PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
1
Issue
18
Year of publication
1999
Pages
4271 - 4275
Database
ISI
SICI code
1463-9076(1999)1:18<4271:PEOALM>2.0.ZU;2-I
Abstract
We study a lattice model of an associating A-B binary mixture, which differ s from the one originally proposed by Lin and Taylor (Phys. Rev. E, 1994, 4 9, 2058 and Phys. Rev. Lett., 1994, 73, 2863) because it allows interaction s between all pairs of particles. This model can be mapped onto an Ising mo del with renormalized coupling parameters. The global phase diagram of the mixture is obtained as a function of the physical parameters. The appearanc e of closed loops of immiscibility is analysed in terms of the coupling par ameters.