The electronic structure and magnetic properties of doped manganites surfac
es are investigated. It is assumed that, at the outermost layer, the enviro
nment of the Mn ions does not have cubic symmetry. The e(g), orbitals are s
plit and the double exchange mechanism is weakened. The charge state of the
Mn ions is modified, and the magnetic ordering of the spins tends to be an
tiferromagnetic. The surface magnetization and the dependence of the transp
ort properties through the resulting surface barrier on applied magnetic fi
eld and temperature is analyzed. [S0163-1829(99)02430-3].