Preparation and catalytic activity of polymer-bound 1,10-phenanthroline and its complexes

Authors
Wang, RM Li, SB Wang, YP Chang, Y He, YF Lei, ZQ Feng, HX
Citation
Rm. Wang et al., Preparation and catalytic activity of polymer-bound 1,10-phenanthroline and its complexes, REACT FUNCT, 42(1), 1999, pp. 87-92
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
REACTIVE & FUNCTIONAL POLYMERS
ISSN journal
13815148 → ACNP
Volume
42
Issue
1
Year of publication
1999
Pages
87 - 92
Database
ISI
SICI code
1381-5148(19990915)42:1<87:PACAOP>2.0.ZU;2-O
Abstract
Polymer-bound 1,10-phenanthroline (PS-phen) has been prepared by reaction o f chloromethylated polystyrene with 5-amino-1,10-phenanthroline. The polyme r-bound ligand and its complexes (PS-phenFephen) were characterized by IR s pectroscopy and XPS. The polymer bound ferric complexes, which are N,N,N,N- type complexes, show high catalytic selectivity in the oxidation of substit uted benzene. (C) 1999 Elsevier Science B.V. All rights reserved.