Thermodynamics of complexation of copper(II) and zinc(II) salts with dipyrrolylmethenes in n-propanol

Authors
Pashanova, NA Berezin, MB Antina, EV Semeikin, AS
Citation
Na. Pashanova et al., Thermodynamics of complexation of copper(II) and zinc(II) salts with dipyrrolylmethenes in n-propanol, RUSS J C CH, 25(9), 1999, pp. 658-660
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
25
Issue
9
Year of publication
1999
Pages
658 - 660
Database
ISI
SICI code
1070-3284(199909)25:9<658:TOCOCA>2.0.ZU;2-L
Abstract
Thermodynamic parameters for complexation of Cu(II) and Zn(II) with 3,3',4, 4',5,5'-hexamethyl- and 3,3',5,5'-tetramethyl-4,4'-diethyldipyrrolylmethene s (structural fragments of the porphyrin molecules) in n-propanol are studi ed calorimetrically and spectrophotometrically. It is found that the comple xes formed are destructed in solutions of metal nitrates at salt concentrat ions above 1 x 10(-3) mol l(-1). The influence of the functional substituen ts and the nature of cation on the thermodynamic parameters of complexation is discussed.