Endurable water-repellent coated layers have been formed on safety glasses
for automobiles via a sol-gel based spray coating process. Coated films are
composed of a silica underlayer ( similar to 800 Angstrom) and a fluorocar
bon layer in which the formed silica shows a definite surface roughness and
acts as the enhancement factor for chemical and mechanical durability. Dur
ability is a function of the degree of surface roughness, structural finene
ss and homogeneity. Dual stage aging in silica sol controls a wide range of
surface roughness. Water-repellency is degraded gradually by a combination
of sunlight (ultraviolet), water, and abrasion. Spray coating on large siz
e and curved safety glasses was successfully carried out. (C) 1999 Elsevier
Science S.A. All rights reserved.