Structure of the alloy Ti50Ni48.7Co1.3

Citation
Z. Lekston et al., Structure of the alloy Ti50Ni48.7Co1.3, ACT CRYST A, 55, 1999, pp. 803-810
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION A
ISSN journal
01087673 → ACNP
Volume
55
Year of publication
1999
Part
5
Pages
803 - 810
Database
ISI
SICI code
0108-7673(19990901)55:<803:SOTAT>2.0.ZU;2-P
Abstract
The structure of the R phase of the alloy Ti50Ni48.7Co1.3 was determined by the crystallogeometric analysis of martensitic transformations in titanium nickelide. This analysis is based on the concept of cooperative thermal vi brations of the (110)-like planes in the b.c.c. and B2 structures and their freezing (transformation to static displacements) at the point of the phas e transition. The space group of the R phase is trigonal P31m with a hexago nal Bravais lattice. The validity of the R-phase structure determination is confirmed by an X-ray diffraction pattern that was obtained at room temper ature using Cu K alpha radiation. The Rietveld procedure was used to compar e the calculated and experimental X-ray diffraction patterns. The proposed structural model of the R phase agrees satisfactorily with the experimental data.