Influence of defects on the phase-boundary movement in a stage transformation of lithium-graphite intercalation compounds

Citation
A. Funabiki et al., Influence of defects on the phase-boundary movement in a stage transformation of lithium-graphite intercalation compounds, CARBON, 37(10), 1999, pp. 1591-1598
Citations number
30
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CARBON
ISSN journal
00086223 → ACNP
Volume
37
Issue
10
Year of publication
1999
Pages
1591 - 1598
Database
ISI
SICI code
0008-6223(1999)37:10<1591:IODOTP>2.0.ZU;2-L
Abstract
The influence of defects on the phase-boundary movement in the stage transf ormation from random stage (dilute stage 1) to stage 4 of lithium-graphite intercalation compounds was investigated using highly oriented pyrolytic gr aphite (HOPG). Potential-step chronoamperometry and in situ optical microsc opy coupled with micro Raman spectroscopy were used to clarify macroscopic and microscopic influence of defects. Potential-step chronoamperometry conf irmed that the diffusion limited rate of the phase-boundary movement in the bulk of HOPG was independent of the crystallinity of the samples. This res ult indicates that defects have macroscopically no appreciable influence on the phase-boundary movement. In situ optical microscopy on the basal plane of HOPG revealed that the nucleation and growth of the stage-4 phase took place quite inhomogeneously in the initial stage. The rate of the phase-bou ndary movement in the surface region of HOPG was roughly evaluated to be in the range of 5 to 10 mu m min(-1). The phase-boundary movement was serious ly retarded by cracks formed on the basal plane during the stage transforma tion. (C) 1999 Elsevier Science Ltd. All rights reserved.