Structures and properties of (TMEO-ST-TTP)(2)AsF6

Citation
Y. Misaki et al., Structures and properties of (TMEO-ST-TTP)(2)AsF6, CHEM LETT, (9), 1999, pp. 859-860
Citations number
20
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
9
Year of publication
1999
Pages
859 - 860
Database
ISI
SICI code
0366-7022(199909):9<859:SAPO(>2.0.ZU;2-M
Abstract
The title material, where TMEO-ST-TTP is 2-[4,5-bis(methylthio)-1,3-diselen ol-2-ylidene)-5-(4,5-ethylendioxy-1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiap entalene, shows metallic conducting behavior down to 4.2 K. X-Ray structure analysis reveals it has the beta-type array of donors in the BEDT-TTF salt s. A tight-binding band calculation suggests the present salt has a quasi-o ne-dimensional Fermi surface.