Structure of azabismocines, hexacoordinate pentavalent organobismuth compounds

Authors
Minoura, M Kanamori, Y Miyake, A Akiba, KY
Citation
M. Minoura et al., Structure of azabismocines, hexacoordinate pentavalent organobismuth compounds, CHEM LETT, (9), 1999, pp. 861-862
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
9
Year of publication
1999
Pages
861 - 862
Database
ISI
SICI code
0366-7022(199909):9<861:SOAHPO>2.0.ZU;2-P
Abstract
Azabisomocine derivatives having a pentavalent bismuth and a nitrogen at 1, 5-position were synthesized. The X-ray structural analysis reveals that the se compounds have hexacoordinate distorted octahedral geometry which is cau sed by transannular bond formation between the bismuth and the nitrogen.