Synthesis, structure, and reactivities of the eta(1):eta(6)-mu(2)-aryl alkynyl diruthenium complex. X-ray structure of [Cp(PPh3)(2)Ru(eta(1):eta(6)-mu(2)-C CC6H4Me-p)RuCp*]PF6 (Cp = eta(5)-C5H5, Cp* = eta(5)-C5Me5)

Authors
Matsuzaka, H Sato, Y Okimura, H Ishii, T Yamashita, M Kitagawa, S Kondo, M Shiro, M Yamasaki, M
Citation
H. Matsuzaka et al., Synthesis, structure, and reactivities of the eta(1):eta(6)-mu(2)-aryl alkynyl diruthenium complex. X-ray structure of [Cp(PPh3)(2)Ru(eta(1):eta(6)-mu(2)-C CC6H4Me-p)RuCp*]PF6 (Cp = eta(5)-C5H5, Cp* = eta(5)-C5Me5), CHEM LETT, (9), 1999, pp. 865-866
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
9
Year of publication
1999
Pages
865 - 866
Database
ISI
SICI code
0366-7022(199909):9<865:SSAROT>2.0.ZU;2-2
Abstract
Preparation of a eta(1):eta(6)-mu(2)-aryl alkynyl diruthenium complex [Cp(P Ph3)(2)Ru(eta(1):eta(6)-mu(2)-C=CC6H4Me-p)RuCp*]Cl (2 . Cl) [Cp = eta(5)-C5 H5, Cp* = eta(5)-C5Me5] and its reactions with electrophile or CO are repor ted. The structure of 2 . PF6 has been determined by X-ray crystallography.