Acid strength of sulfated zirconia inferred from catalytic isobutane conversion

Authors
Citation
D. Fraenkel, Acid strength of sulfated zirconia inferred from catalytic isobutane conversion, CHEM LETT, (9), 1999, pp. 917-918
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
9
Year of publication
1999
Pages
917 - 918
Database
ISI
SICI code
0366-7022(199909):9<917:ASOSZI>2.0.ZU;2-0
Abstract
The kinetics of the catalytic conversion of isobutane under gas-phase fixed -bed flow conditions over sulfated zirconia (SZ), when compared with those of other strong solid acids of known acidity, suggests that SZ may be a ver y strong solid superacid; this conclusion disagrees with recent reports cla iming that SZ is not a superacid, and supports older claims, based on acidi ty tests with Hammett indicators, that SZ may have H-O of < -16.