Zn. Bao et Aj. Lovinger, Soluble regioregular polythiophene derivatives as semiconducting materialsfor field-effect transistors, CHEM MATER, 11(9), 1999, pp. 2607-2612
Soluble regioregular polythiophene derivatives with chiral alkyl side chain
s, bulky side chains, and carboxylic side chains have been synthesized. The
ir thin-film field-effect transistor performance and structural characteris
tics have been investigated. The above properties were found to be strongly
affected by the nature of the side chains. Poor molecular ordering and low
crystallinity were found for regioregular polythiophenes with bulky or car
boxylic-substituted side chains, and their resulting transistor devices sho
wed poor field-effect mobilities (less than 10(-5)-10(-4) cm(2)/(V s)). A c
hiral alkyl-substituted regioregular polythiophene showed high crystallinit
y. However, its pi-pi overlap distance between the polythiophene backbones
increase substantially (i.e., to similar to 4.3 vs 3.8 Angstrom for regiore
gular poly(3-hexylthiophene) (PHT)) through the introduction of methyl bran
ches in the side chains. The field-effect mobility of this polymer is reaso
nably high for solution-processable conjugated polymers (i.e., of the order
of 10(-3) cm(2)/(Vs)), but is still an order of magnitude lower than for r
egioregular PHT. These studies provide an initial basis for further structu
ral design and molecular engineering of soluble regioregular polythiophenes
with potentially improved transistor performance.