Organolanthanides as single component homogeneous catalysts for isoprene-hex-1-ene co-polymerisation

Authors
Barbier-Baudry, D Dormond, A Desmurs, P
Citation
D. Barbier-baudry et al., Organolanthanides as single component homogeneous catalysts for isoprene-hex-1-ene co-polymerisation, CR AC S IIC, 2(7-8), 1999, pp. 375-378
Citations number
26
Categorie Soggetti
Chemistry
Journal title
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE
ISSN journal
13871609 → ACNP
Volume
2
Issue
7-8
Year of publication
1999
Pages
375 - 378
Database
ISI
SICI code
1387-1609(199907/08)2:7-8<375:OASCHC>2.0.ZU;2-0
Abstract
Bisallylansalanthanide complexes act as single component catalysts of diene polymerisation; from an equimolar mixture of isoprene and hex-1-ene, a co- polymer hex-1-ene/isoprene = 1:10 is obtained, this copolymer is essentiall y formed of 1,4-transpolyisoprene blocks separated by only one inserted hex yl group. (C) 1999 Academie des sciences/Editions scientifiques et medicale s Elsevier SAS.