We have investigated epitaxial YBCO films by Perturbed gamma gamma-Angular
Correlation Spectroscopy (PAC) using In-111 probe atoms. The probes substit
ute on the yttrium lattice site and hyperfine parameters have been determin
ed unambiguously. Excellent agreement is achieved with full potential elect
ric field gradient (efg) calculations. Good reproducibility has been achiev
ed by our preparation method allowing us to study the influence of oxygen m
otion on the structural orthorhombic to tetragonal phase transition.