M. Uhrmacher et al., Ionic and electronic transport in In2S3 studied via perturbed angular correlation spectroscopy, HYPER INTER, 121(1-8), 1999, pp. 371-375
We report on Perturbed Angular Correlation measurements in polycrystalline
In2S3 samples in the temperature range from 8 K to 1000 K where two differe
nt crystallographic phases beta and alpha occur. As probes, implanted In-11
1 nuclei have been used. The three observed EFGs are attributed to probes r
esiding substitutionally in the different sulfur-octahedra and -tetrahedra
of beta-In2S3. A strong damping between 150 K and 300 K has been attributed
to EFG fluctuations following the In-111(EC)Cd-111 decay. The alpha-phase
(above 680 K) is characterized by a different dynamical damping of the pert
urbation functions, caused by mobile In atoms. Therefore, the semiconductor
In2S3 shows, in two different temperature ranges, dynamical PAC-spectra wh
ich correspond to different types of mobile charge carriers. Since In-111 i
s a self atom in In2S3, this compound is an ideal substance to study the ch
arge transport phenomena by the PAC technique.