Tris 1-nitroso-2-naphtholate complex of ruthenium(II): An efficient building unit for polynuclear complexes

Authors
Das, AK Rueda, A Falvello, LR Peng, SM Bhattacharya, S
Citation
Ak. Das et al., Tris 1-nitroso-2-naphtholate complex of ruthenium(II): An efficient building unit for polynuclear complexes, INORG CHEM, 38(19), 1999, pp. 4365
Citations number
45
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
19
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990920)38:19<4365:T1CORA>2.0.ZU;2-9
Abstract
Reaction of 1-nitroso-2-naphthol (HL) with ruthenium trichloride afforded t he facial isomer of [Ru-II(L)(3)](-) (1), which has been isolated as the tr iethylammonium salt. Using [Ru-II(L)(3)](-) as a tridentate ligand, a heter ometallic trinuclear complex, viz., [{Ru(L)(3)}(2)Ni] (2), has been synthes ized.