Generally, a three-step heat treatment consisting of austenitizing, quenchi
ng and austempering is necessary to produce ADI, Using an in situ heat trea
tment the nodular cast iron casting was ejected at a temperature above 870
degrees C and directly quenched to 300-400 degrees C for austempering. Beca
use the austenitization is no longer necessary in this method a significant
reduction of energy and production time can be achieved. To guarantee the
casting to be ejected with a well defined temperature distribution a perman
ent mould casting process was used.
For predicting the microstructural evolution during the solidification and
the subsequent ausferrite reaction during austempering a simulation model w
as developed for ternary Fe-C-Si alloys. For the simulation it was assumed
that eutectic grains are formed below the eutectic temperature and that the
ir growth rate is controlled by carbon diffusion through the austenite shel
l. Carbon and silicon concentrations at the phase interfaces are calculated
from the Fe-C-Si phase diagram obtained from the thermodynamic phase equil
ibrium calculation tool, ChemApp(TM) The pursuing solid state transformatio
n is described by the growth of the ferrite shell into the austenite, which
is controlled by carbon diffusion in a quasi-steady state. The distributio
n of temperature, nodule counts, nodule sizes and phase fractions in the ca
sting were calculated from mass conservation. The transformation from auste
nite to ausferrite was calculated by the modified Avrami equation with the
additivity rule. The simulation results were verified by experimental resul
ts. Mechanical properties show interesting potentials for application.