Laser remelting experiments at 50 and 100 mu m/s scanning velocity were emp
loyed to study the microstructure in Fe-C-Si alloys with compositions in th
e range: 3.2-4.2 wt.% C and 1-3 wt,% Si. Due to the geometry of the liquid
pool, different growth velocities were obtained during remelting; zero at t
he bottom of the pool and a rate close to the laser velocity near the surfa
ce. Solidification starts with gray iron with vermicular graphite morpholog
y and changes to a white ledeburitic structure near the surface. The measur
ed velocity for the gray-white transition was about 43 mu m/s for all analy
zed alloys. Theoretical models show that this transition velocity is highly
sensitive to the Si-content in the alloy, which was not verified by the ex
periments. Changes in composition of C and Si during processing explain the
observed disagreement between experimental results and theory.