Effect of functionality levels and compatibility of polycarbonate blends with maleic anhydride grafted ABS

Citation
S. Balakrishnan et al., Effect of functionality levels and compatibility of polycarbonate blends with maleic anhydride grafted ABS, J APPL POLY, 74(8), 1999, pp. 2102-2110
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
74
Issue
8
Year of publication
1999
Pages
2102 - 2110
Database
ISI
SICI code
0021-8995(19991121)74:8<2102:EOFLAC>2.0.ZU;2-9
Abstract
ABS was melt grafted with maleic anhydride at three different levels of 1, 2, and 3 wt %. These three different modified ABSs were melt blended with p olycarbonate using a single-screw extruder to choose a suitable maleic anhy dride grafting level on ABS for better performance. For the compatibility s tudy, binary blends of polycarbonate with ABS and maleic anhydride-grafted ABS were prepared over the entire range of compositions. Compatibility of t hese blends was studied using a Dynamic Mechanical Analyzer and by Differen tial Scanning Calorimetry. Both techniques suggest more partial compatibili ty for modified blend systems. In addition to this, DSC thermograms show mu ltiple peaks between the transition points of ABS fractions and polycarbona te fractions for the polycarbonate/maleic anhydride-grafted ABS blends. The se multiple peaks are characteristic of better partial compatibility with f ine microstructure. (C) 1999 John Wiley & Sons, Inc.