Control of the coordination mode of NO2- by the nature of the amine ligand. Crystal structure of the neutral zigzag polymeric compound [mer-Ni(N-(2-aminoethyl)-1,3-propanediamine)-(NO2)(2)] (I)

Authors
Wen, RW Somoza, F Bernal, I Fronczek, FR
Citation
Rw. Wen et al., Control of the coordination mode of NO2- by the nature of the amine ligand. Crystal structure of the neutral zigzag polymeric compound [mer-Ni(N-(2-aminoethyl)-1,3-propanediamine)-(NO2)(2)] (I), J COORD CH, 48(4), 1999, pp. 443-448
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
00958972 → ACNP
Volume
48
Issue
4
Year of publication
1999
Pages
443 - 448
Database
ISI
SICI code
0095-8972(1999)48:4<443:COTCMO>2.0.ZU;2-5
Abstract
A polymeric zigzag complex, [mer-Ni(N-(2-aminoethyl)-1,3-propanediamine)(NO 2)(2)] (I), containing a bridging mu-nitro(N,O), was obtained and its cryst al structure was determined. Magnetic studies show the compound is antiferr omagnetic. These results contrast to those for [Ni(3,3'-diamino-N-methyldip ropylamine)(NO2)(2)] (II), which is a monomer.