Magnetic properties of CrF4 and two fluorochromate(IV) complexes with xenon fluorides, XeF2 center dot CrF4 and (XeF5+CrF5-,)(4)center dot XeF4

Authors
Mazej, Z Darriet, J Grannec, J Lutar, K Tressaud, A Zemva, B
Citation
Z. Mazej et al., Magnetic properties of CrF4 and two fluorochromate(IV) complexes with xenon fluorides, XeF2 center dot CrF4 and (XeF5+CrF5-,)(4)center dot XeF4, J FLUORINE, 99(1), 1999, pp. 25-28
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
99
Issue
1
Year of publication
1999
Pages
25 - 28
Database
ISI
SICI code
0022-1139(199910)99:1<25:MPOCAT>2.0.ZU;2-#
Abstract
Several series of fluorocompounds containing tetravalent chromium have been recently prepared. In XeF2. CrF4 and (XeF5+CrF5-)(4) . XeF4, Cr(IV) is loc ated in fluorine octahedra which share corners to form infinite chains of ( CTF4F2/2)(n)(-n). The magnetic behaviour of these compounds has been invest igated in order to deduce the magnetic characteristics of Cr(IV); antiferro magnetic superexchange interactions are present within the chains. Magnetic studies of amorphous CrF4 have also been performed. (C) 1999 Elsevier Scie nce S.A. All rights reserved.