Subaqueous disposal is a technique that can, under suitable circumstances,
delay or mitigate the release of material containing high levels of dissolv
ed compounds, for example, acid rock drainage, into the surrounding environ
ment. The technique places the material in question under a relatively iner
t cap of Lighter fluid in a deep basin, such as that left after mining. In
many situations, because of low diffusion rates, the material may be consid
ered as being isolated from the environment. However, there are a number of
naturally occurring physical mechanisms that can quite efficiently bring t
his material to the surface, and hence, to the surrounding environment. We
describe a modeling application to a deep and steep-sided chemically strati
fied lake using an extended version of the lake and reservoir water quality
model, DYRESM, incorporating algorithms for detailed ice cover, heat fluxe
s, and also internal wave-driven boundary mixing. Sheltering and shading of
the meteorological forcing is taken into account in the model. Both the fi
eld data and the model confirm the capping effects of the freshwater cap (S
< 0.7 g/L) overlying the relatively salty water (S > 0.85 g/L) in the pit.
Examination of the mechanistically determined vertical eddy diffusivities
suggest that at depths below the surface mixed layer, double diffusion domi
nates over vertical mixing due to bottom-generated turbulence stemming from
basin-scale internal waves. The ability of the model to simulate for perio
ds longer than about 6 months is not addressed in this study.