Feedback optimization of pulse width in the SORC sequence

Citation
Jl. Schiano et al., Feedback optimization of pulse width in the SORC sequence, J MAGN RES, 140(1), 1999, pp. 84-90
Citations number
19
Categorie Soggetti
Chemistry & Analysis","Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MAGNETIC RESONANCE
ISSN journal
10907807 → ACNP
Volume
140
Issue
1
Year of publication
1999
Pages
84 - 90
Database
ISI
SICI code
1090-7807(199909)140:1<84:FOOPWI>2.0.ZU;2-L
Abstract
A method for increasing the signal-to-noise ratio (SNR) of nuclear quadrupo le resonance (NQR) measurements by automatically adjusting a pulse paramete r in real-time is presented. This approach is useful in situations where th e optimal pulse parameters cannot be chosen beforehand due to lack of knowl edge regarding the system. For example, NQR provides a means for detecting explosives by revealing the presence of N-14. In this particular applicatio n, the distance between the search coil and the explosive, as well as the t emperature of the explosive, is unknown. As a result, a fixed set of pulse parameters will not yield the largest SNR for all possible search applicati ons. This paper describes a feedback algorithm that uses measurements of th e NQR signal to automatically adjust the pulse width in the strong off-reso nant comb sequence to maximize the SNR of the NQR measurement. Experimental results obtained using a sample of sodium nitrite are presented. (C) 1999 Academic Press.