THE PREPARATION AND X-RAY STRUCTURE OF [M((SEPPH2)(2)N)(2)], M=NI, PD, PT

Authors
PAPADIMITRIOU C VELTSISTAS P NOVOSAD J CEAOLIVARES R TOSCANO A GARCIA PGY LOPEZCARDOSA M SLAWIN AMZ WOOLLINS JD
Citation
C. Papadimitriou et al., THE PREPARATION AND X-RAY STRUCTURE OF [M((SEPPH2)(2)N)(2)], M=NI, PD, PT, Polyhedron, 16(16), 1997, pp. 2727-2729
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
16
Year of publication
1997
Pages
2727 - 2729
Database
ISI
SICI code
0277-5387(1997)16:16<2727:TPAXSO>2.0.ZU;2-#
Abstract
Reaction of [Ni(CH3CO)(2)]4H(2)O, H2PdCl4 or H2PtCl6 with HN[P(Se)Ph-2 ](2) in water/acetone gave the title compounds in good yield. The comp ounds were characterised by IR/Raman, NMR and X-ray crystallography. T he square planar metal centres form parts of spiro pseudo-boat rings. The X-ray structures allow comparison of the radii of Pt and Pd atoms. (C) 1997 Elsevier Science Ltd.